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Left undisturbed I would agree there is a blanket of CO2 on top of the wort/beer.
However, as soon as the turbulence from opening the fermenter stirs the air with CO2, that blanket is mixed up.
Add hops by pouring them into the liquid or throwing in a hop bag and more mixing occurs.
The active yeast will push the mixture out the blowoff and if any O2 was inadvertently introduced to the liquid they will consume it.
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